Integration of plasmonic AgPd alloy nanoparticles with single-layer graphitic carbon nitride as Mott-Schottky junction toward photo-promoted H2 evolution

Sci Rep. 2022 Aug 9;12(1):13583. doi: 10.1038/s41598-022-17238-4.


Plasmonic AgPd alloy nanoparticles (AgPdNPs) decorated on single-layer carbon nitride (AgPdNPs/SLCN) for the designing of the Mott-Schottky junction were constructed with the ultrasonically assisted hydrothermal method and used toward photo evolution H2 from formic acid (FA) at near room temperature (30 °C). The Pd atom contains active sites that are synergistically boosted by the localized surface plasmon resonance (LSPR) effect of Ag atoms, leading to considerably enhanced photocatalytic properties. The photoactive AgPdNPs/SLCN obtained supreme catalytic activity to produce 50 mL of gas (H2 + CO2) with the initial turnover frequency of 224 h-1 under light irradiation. The catalyst showed stable catalytic performance during successive cycles.

PMID:35945424 | PMC:PMC9363438 | DOI:10.1038/s41598-022-17238-4


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