Magnetic cobalt oxide supported organosilica-sulfonic acid as a powerful nanocatalyst for the synthesis of tetrahydrobenzo[a]xanthen-11-ones

Sci Rep. 2023 Aug 29;13(1):14134. doi: 10.1038/s41598-023-41234-x.


A novel core-shell structured magnetic cobalt oxide supported organosilica-sulfonic acid (Co3O4@SiO2/OS-SO3H) nanocomposite is prepared through a low-cost, simple, and clean method. The characterization of Co3O4@SiO2/OS-SO3H was performed by using Fourier transform infrared (FT-IR) spectroscopy, thermal gravimetric analysis (TGA), powder X-ray diffraction (PXRD), energy dispersive X-ray (EDX) spectroscopy, scanning electron microscopy (SEM), vibrating sample magnetometer (VSM), and transmission electron microscopy (TEM). The TGA and FT-IR results illustrate the high stability of the designed nanocomposite. The SEM image showed a size of about 40 nm for the Co3O4@SiO2/OS-SO3H nanoparticles. Furthermore, according to the result of VSM analysis, the saturation magnetization of this nanocomposite was about 25 emu/g. This novel material was used as an efficient nanocatalyst for the synthesis of biologically active tetrahydrobenzo[a]xanthen-11-one derivatives. These products were obtained in high to excellent yields under green conditions. The recoverability and reusability of this catalyst were also investigated under applied conditions.

PMID:37644117 | PMC:PMC10465481 | DOI:10.1038/s41598-023-41234-x


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