The electro-oxidation of primary alcohols via a coral-shaped cobalt metal-organic framework modified graphite electrode in neutral media

Sci Rep. 2022 May 20;12(1):8560. doi: 10.1038/s41598-022-12200-w.

ABSTRACT

The electro-oxidation of alcohols into corresponding aldehydes achieved enormous attention. However, numerous challenges remain in exploring catalytic systems with high conversion efficiency and selectivity. Considering the worldwide attention toward metal-organic frameworks (MOFs) as outstanding crystalline porous materials, many chemists have been encouraged to use them in organic transformations. In this study, a novel coral-shaped cobalt organic framework was grown onto the surface of a functionalized graphite electrode (Co-MOF/C) to fabricate an efficient modified electrode in the electro-oxidation alcohols. The modified Co-MOF/C electrode showed high stability, large surface area, rich pores, and good conductivity as a desirable water-stable working electrode for selective oxidation of alcohols into aldehydes in good to excellent yields under a diffusion-controlled process.

PMID:35595773 | PMC:PMC9122998 | DOI:10.1038/s41598-022-12200-w

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